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Ultimecia because she was always surrounded by awesome music. Plus, I find it quite fun to speculate about her origins. The most likely theory is kind of sad.
Ultimecia. Even though losing the aeons for the final battle was sad and all and the yevon-aeon music was AWESOME(!!!), Ultimecia's three forms + Griever and the The Extreme and the fact that the entire final battle sequence wouldn't require a maximum of 14 regular attacks when levelled up a little. And Ultimecia has a scheme, Yevon's just lost his mind entirely.
Although both of them are one the 'wtf last minute ultimate villian' list, I'd say Ultimecia. Partially because the Rinoa-Ultimecia theory, if true, is the only thing I like about Rinoa.
And because Yu Yevon is not even a character